by MrPEX on Thu Oct 26, 2006 1:45 pm
Hi,
RB invited me for a comment. Thanks!
When PEX Tubing is embedded in concrete, or similar, its thermal expansion and contraction is restrained. That is in longitudinal direction, and in radial direction - outwards. At a temperature increase, some expansion -inwards - will happen = a very slight inside diameter decrease. But no movement in longitudinal direction is possible, so instead there will be a compression stress in the material in that direction. The level of the stress is equal to the Youngs Modulus times the relative expansion withheld. I could write more about the stress level, but it is not very high, since the Modulus is low.
So what about that stress? Any harm with it? Well, genarally PEX is very resistant to Stress Cracking, that is formation of a an initial crack, and then a crack propagation. The reason is the molecular network. Stresses in molecular chains are evened out between the different chains at the crosslinkinks. We have a net - instead of individual fibers. The network will even out peak stresses and distribute the stress fairly evenly inside the material, in this way avoiding excessive stresses that could lead to rupture (crack) and also crack propagation.
But there is a difference here for various types of PEX... For PEX processes where the crosslinks are formed when the material is melted (hot), the formation of crosslinks are not hindered by the crystals in the material during the "curing". That is, for example, PEX-a and PEX-d processes. For PEX-b and PEX-c, etc., the crosslinks are restricted to occur outside the existing crystals in the material, leading to a more un-even distribution of crosslinks. And a corresponding lessor ability to even out peak stresses. But this higher degree of imperfection in those processes are not sufficient to cause any problem in normal applications. Only at very high and repeated stress exposure (fatigue), cracks and crack propagation has resulted for those materials (while not at all for "warm crosslinked" materials).
Copper, on the other hand, is proven to develop excessive stresses when expansion/contraction is withheld. Stresses, that lead to decrease in crystal sizes over time, and subsequent embrittleness, that often has lead to failure over time. But mainly at fairly high temperature variations, and after many cycles (long time), and comparatively long straight lengths installed in this way.
Did this shred any light, - or just confuse...??
Best regards,
Mr PEX